Carbon-Nanofillers, Nanofiller, Polymer, Resin, metal oxide


Epoxy resins have been the subject of many studies as a consequence of their extensive usage in recent years. The brittleness and low resistance to propagation and crack initiation of epoxy resins are well-recognized characteristics. Therefore, in recent years, experts have concentrated on increasing epoxy resin's fracture resistance. Adding inorganic nanoparticles like titanium dioxide (TiO2) TiO2, silica (SiO2), carbon black, alumina (Al2O3), and others to the polymer matrix is one of the most investigated techniques in polymer science. Despite having a modest nanofiller content, the resulting nanocomposites may enhance their thermal, mechanical, rheological, electrical, and optical characteristics. These nanocomposites are an alternative to metal-based materials. They have great promise as multifunctional materials in a range of applications, including optoelectronic devices, semiconductor devices, civil engineering, automotive, and aerospace. To show potential future directions and market prospects for polymer nanocomposites reinforced with TiO2 nanoparticles, current results, and trends have been examined and highlighted. In addition, the current review surveys many studies that highlighted using nanoparticles as reinforcement, their different structure, the interface, and the geometry and structure of the resulting nano-materials reinforced resin.


M. Frigione and M. Lettieri, "Recent advances and trends of nanofilled/nanostructured epoxies" Materials, vol. 13, no. 15, p. 3415, 2020. https://doi.org/10.3390/ma13153415

S. Hassan, M. ., K. Ibrahim, Y. ., & I. Marhoon, I. I"Investigation of Mechanical Characteristics Of (Epoxy-Resole Blend) Matrix Hybrid Composite". Journal of Engineering and Sustainable Development, vol. 26, no. 3, 27–32. 2022. https://doi.org/10.31272/jeasd.26.3.4

M. Kadhim, B. ., & M. Oweed, K. "Study The Effect Of Different Additives On Crack Repair Epoxy". Journal of Engineering and Sustainable Development, vol. 25, no. 3, pp:74–80. 2021. https://doi.org/10.31272/jeasd.25.3.8

Romero, M., Mombrú, D., Pignanelli, F., Faccio, R., & Mombrú, A. W. Hybrid Organic-Inorganic Materials and Interfaces With Mixed Ionic-Electronic Transport Properties: Advances in Experimental and Theoretical Approaches". Frontiers in Chemistry, 10, 892013. 2022 https://doi.org/10.3389/fchem.2022.892013

A. Chlob, H. ., & M. Fenjan, R.. "Studying The Mechanical Properties Of Hybrid Composites Using Natural Additives With Epoxy". Journal of Engineering and Sustainable Development, vol. 26, no. 1, pp: 15–26. 2022. https://doi.org/10.31272/jeasd.26.1.2

Dawood Salman, S. "Experimental Measurements of the Mechanical Behavior of the Composite Materials and Hybrid Materials Subject to Tensile Test". Journal of Engineering and Sustainable Development, vol. 17, no. 1, pp:162–170. 2013. Retrieved from https://jeasd.uomustansiriyah.edu.iq/index.php/jeasd/article/view/1100.

Basim Abdul-Hussein, A. ., Saadi Abdel Kareem, E., & Subhi Atallah, M. . . (). "Effect Of Carbon Nano Tubes On Erosion Wear Of Carbon Fiber, Glass Fiber & Kevlar Fiber Reinforced Unsaturated Polyester Composites". Journal of Engineering and Sustainable Development, vol. 22, no. 4, p:74–89. 2018. Retrieved from https://jeasd.uomustansiriyah.edu.iq/index.php/jeasd/article/view/426

W. Duan, Y. Chen, J. Ma, W. Wang, J. Cheng, and J. Zhang, "High-performance graphene reinforced epoxy nanocomposites using benzyl glycidyl ether as a dispersant and surface modifier," Composites Part B: Engineering, vol. 189, p. 107878, 2020. https://doi.org/10.1016/j.compositesb.2020.107878

A. Kumar, K. Sharma, and A. R. Dixit, "A review on the mechanical and thermal properties of graphene and graphene-based polymer nanocomposites: understanding of modeling and MD simulation," Molecular Simulation, vol. 46, no. 2, pp. 136-154, 2020. https://doi.org/10.1080/08927022.2019.1680844

S. Z. Al Sheheri, Z. M. Al-Amshany, Q. A. Al Sulami, N. Y. Tashkandi, M. A. Hussein, and R. M. El-Shishtawy, "The preparation of carbon nanofillers and their role on the performance of variable polymer nanocomposites," Designed monomers and polymers, 2019. https://doi.org/10.1080/15685551.2019.1565664 https://doi.org/10.1080/15685551.2019.1565664

M. K. Shukla and K. Sharma, "Effect of carbon nanofillers on the mechanical and interfacial properties of epoxy based nanocomposites: A review," Polymer Science, Series A, vol. 61, no. 4, pp. 439-460, 2019. https://doi.org/10.1134/s0965545x19040096

V. Kumar, M. N. Alam, A. Manikkavel, M. Song, D.-J. Lee, and S.-S. Park, "Silicone rubber composites reinforced by carbon nanofillers and their hybrids for various applications: A review," Polymers, vol. 13, no. 14, p. 2322, 2021. https://doi.org/10.3390/polym13142322

S. K. Gupta and D. K. Shukla, "Effect of stress rate on shear strength of aluminium alloy single lap joints bonded with epoxy/nanoalumina adhesives," International Journal of Adhesion and Adhesives, vol. 99, p. 102587, 2020. https://doi.org/10.1016/j.ijadhadh.2020.102587

Kadhium Mohammed, R. ., Abdel-Hamead, A. A. ., & Mohammed Othman, F. "Effect of nano-alumina on microstructure and mechanical properties of recycled concrete". Journal of Engineering and Sustainable Development, vol. 22, no.2, pp:90–103. 2018. https://doi.org/10.31272/jeasd.2018.2.8

V. Tomer, G. Polizos, E. Manias, and C. Randall, "Epoxy-based nanocomposites for electrical energy storage. I: Effects of montmorillonite and barium titanate nanofillers," Journal of Applied Physics, vol. 108, no. 7, p. 074116, 2010. https://doi.org/10.1063/1.3487275

S. Siddabattuni, T. P. Schuman, and F. Dogan, "Improved polymer nanocomposite dielectric breakdown performance through barium titanate to epoxy interface control," Materials Science and Engineering: B, vol. 176, no. 18, pp. 1422-1429, 2011. https://doi.org/10.1016/j.mseb.2011.07.025

R. Das, P. Pachfule, R. Banerjee, and P. Poddar, "Metal and metal oxide nanoparticle synthesis from metal organic frameworks (MOFs): finding the border of metal and metal oxides," Nanoscale, vol. 4, no. 2, pp. 591-599, 2012. https://doi.org/10.1039/c1nr10944h

A. Rastogi et al., "Impact of metal and metal oxide nanoparticles on plant: a critical review," Frontiers in chemistry, vol. 5, p. 78, 2017. https://doi.org/10.3389/fchem.2017.00078

S. M. Dizaj, F. Lotfipour, M. Barzegar-Jalali, M. H. Zarrintan, and K. Adibkia, "Antimicrobial activity of the metals and metal oxide nanoparticles," Materials Science and Engineering: C, vol. 44, pp. 278-284, 2014. https://doi.org/10.1016/j.msec.2014.08.031

V. Akbari et al., "Surface chemistry of halloysite nanotubes controls the curability of low filled epoxy nanocomposites," Progress in Organic Coatings, vol. 135, pp. 555-564, 2019. https://doi.org/10.1016/j.porgcoat.2019.06.009

S. Horsch, G. Serhatkulu, E. Gulari, and R. M. Kannan, "Supercritical CO2 dispersion of nano-clays and clay/polymer nanocomposites," Polymer, vol. 47, no. 21, pp. 7485-7496, 2006. https://doi.org/10.1016/j.polymer.2006.08.048

M. Rajaei, N. Kim, S. Bickerton, and D. Bhattacharyya, "A comparative study on effects of natural and synthesised nano-clays on the fire and mechanical properties of epoxy composites," Composites Part B: Engineering, vol. 165, pp. 65-74, 2019. https://doi.org/10.1016/j.compositesb.2018.11.089

Y. Yang et al., "Morphology control of nanofillers in poly (phenylene sulfide): A novel method to realize the exfoliation of nanoclay by SiO2 via melt shear flow," Composites science and technology, vol. 75, pp. 28-34, 2013 https://doi.org/10.1016/j.compscitech.2012.11.006 .

H. Xie et al., "Biodegradable near-infrared-photoresponsive shape memory implants based on black phosphorus nanofillers," Biomaterials, vol. 164, pp. 11-21, 2018. https://doi.org/10.1016/j.biomaterials.2018.02.040

T. G. Novak et al., "Low-cost black phosphorus nanofillers for improved thermoelectric performance in PEDOT: PSS composite films," ACS applied materials & interfaces, vol. 10, no. 21, pp. 17957-17962, 2018. https://doi.org/10.1021/acsami.8b03982

P. Gnanasekar, M. Feng, and N. Yan, "Facile synthesis of a phosphorus-containing sustainable biomolecular platform from vanillin for the production of mechanically strong and highly flame-retardant resins," ACS Sustainable Chemistry & Engineering, vol. 8, no. 47, pp. 17417-17426, 2020. https://doi.org/10.1021/acssuschemeng.0c05610

Y. Li et al., "In situ exfoliation of graphene in epoxy resins: a facile strategy to efficient and large scale graphene nanocomposites," ACS applied materials & interfaces, vol. 8, no. 36, pp. 24112-24122, 2016. https://doi.org/10.1021/acsami.6b07492

H. Im and J. Kim, "Thermal conductivity of a graphene oxide–carbon nanotube hybrid/epoxy composite," Carbon, vol. 50, no. 15, pp. 5429-5440, 2012. https://doi.org/10.1016/j.carbon.2012.07.029

C. Huang et al., "Ultratough nacre-inspired epoxy–graphene composites with shape memory properties," Journal of Materials Chemistry A, vol. 7, no. 6, pp. 2787-2794, 2019. https://doi.org/10.1039/c8ta10725d https://doi.org/10.1039/c8ta10725d

C. Huang and Q. Cheng, "Learning from nacre: Constructing polymer nanocomposites," Composites Science and Technology, vol. 150, pp. 141-166, 2017. https://doi.org/10.1016/j.compscitech.2017.07.021

R. M. Laine, J. Choi, and I. Lee, "Organic–inorganic nanocomposites with completely defined interfacial interactions," Advanced Materials, vol. 13, no. 11, pp. 800-803, 2001. https://doi.org/10.1002/1521-4095(200106)13:11<800::aid-adma800>3.0.co;2-g

X.-Z. Ding, Z.-Z. Qi, and Y.-Z. He, "Effect of hydrolysis water on the preparation of nano-crystalline titania powders via a sol-gel process," Journal of Materials Science Letters, vol. 14, no. 1, pp. 21-22, 1995. https://doi.org/10.1007/bf02565273

T. Sugimoto, X. Zhou, and A. Muramatsu, "Synthesis of uniform anatase TiO2 nanoparticles by gel–sol method: 4. Shape control," Journal of Colloid and Interface Science, vol. 259, no. 1, pp. 53-61, 2003. https://doi.org/10.1016/s0021-9797(03)00035-3

C. Calebrese, L. Hui, L. S. Schadler, and J. K. Nelson, "A review on the importance of nanocomposite processing to enhance electrical insulation," IEEE Transactions on Dielectrics and Electrical Insulation, vol. 18, no. 4, pp. 938-945, 2011. https://doi.org/10.1109/tdei.2011.5976079

S. Virtanen et al., "Dielectric breakdown strength of epoxy bimodal-polymer-brush-grafted core functionalized silica nanocomposites," IEEE Transactions on Dielectrics and Electrical Insulation, vol. 21, no. 2, pp. 563-570, 2014. https://doi.org/10.1109/tdei.2014.004415

M. Kurimoto et al., "Permittivity characteristics of epoxy/alumina nanocomposite with high particle dispersibility by combining ultrasonic wave and centrifugal force," IEEE Transactions on Dielectrics and Electrical Insulation, vol. 17, no. 4, pp. 1268-1275, 2010. https://doi.org/10.1109/tdei.2010.5539699

A. Boonchun, P. Reunchan, and N. Umezawa, "Energetics of native defects in anatase TiO 2: a hybrid density functional study," Physical Chemistry Chemical Physics, vol. 18, no. 43, pp. 30040-30046, 2016. https://doi.org/10.1039/c6cp05798e

A. H. Tavakoli et al., "Amorphous alumina nanoparticles: structure, surface energy, and thermodynamic phase stability," The Journal of Physical Chemistry C, vol. 117, no. 33, pp. 17123-17130, 2013. https://doi.org/10.1021/jp405820g

T. Heid, M. Fréchette, and E. David, "Epoxy/BN micro-and submicro-composites Dielectric and thermal properties of enhanced materials for high voltage insulation systems," IEEE Transactions on Dielectrics and Electrical Insulation, vol. 22, no. 2, pp. 1176-1185, 2015. https://doi.org/10.1109/tdei.2015.7076820

I. Pleşa, P. V. Noţingher, S. Schlögl, C. Sumereder, and M. Muhr, "Properties of polymer composites used in high-voltage applications," Polymers, vol. 8, no. 5, p. 173, 2016. https://doi.org/10.3390/polym8050173

C. Rao, P. Thomas, and G. Kulkarni, "Nanocrystals," Synthesis, properties and applications. Springer, Berlin, 2007. https://doi.org/10.1002/352760247x.ch4

G. Tsagaropoulos and A. Eisenberg, "Dynamic mechanical study of the factors affecting the two glass transition behavior of filled polymers. Similarities and differences with random ionomers," Macromolecules, vol. 28, no. 18, pp. 6067-6077, 1995. https://doi.org/10.1021/ma00122a011

T. Lewis, "Interfaces are the dominant feature of dielectrics at the nanometric level," IEEE Transactions on dielectrics and electrical insulation, vol. 11, no. 5, pp. 739-753, 2004. https://doi.org/10.1109/tdei.2004.1349779

M. G. Danikas and T. Tanaka, "Nanocomposites-a review of electrical treeing and breakdown," IEEE Electrical Insulation Magazine, vol. 25, no. 4, pp. 19-25, 2009. https://doi.org/10.1109/mei.2009.5191413

D. Pinto, L. Bernardo, A. Amaro, and S. Lopes, "Mechanical properties of epoxy nanocomposites using titanium dioxide as reinforcement–a review," Construction and Building Materials, vol. 95, pp. 506-524, 2015. https://doi.org/10.1016/j.conbuildmat.2015.07.124

P. Dittanet and R. A. Pearson, "Effect of silica nanoparticle size on toughening mechanisms of filled epoxy," Polymer, vol. 53, no. 9, pp. 1890-1905, 2012. https://doi.org/10.1016/j.polymer.2012.02.052

B. Wetzel, F. Haupert, and M. Q. Zhang, "Epoxy nanocomposites with high mechanical and tribological performance," Composites science and technology, vol. 63, no. 14, pp. 2055-2067, 2003. https://doi.org/10.1016/s0266-3538(03)00115-5

B. Johnsen, A. Kinloch, R. Mohammed, A. Taylor, and S. Sprenger, "Toughening mechanisms of nanoparticle-modified epoxy polymers," Polymer, vol. 48, no. 2, pp. 530-541, 2007. https://doi.org/10.1016/j.polymer.2006.11.038

H. Zhang, Z. Zhang, K. Friedrich, and C. Eger, "Property improvements of in situ epoxy nanocomposites with reduced interparticle distance at high nanosilica content," Acta materialia, vol. 54, no. 7, pp. 1833-1842, 2006. https://doi.org/10.1016/j.actamat.2005.12.009

S. Zhao, L. S. Schadler, R. Duncan, H. Hillborg, and T. Auletta, "Mechanisms leading to improved mechanical performance in nanoscale alumina filled epoxy," Composites Science and Technology, vol. 68, no. 14, pp. 2965-2975, 2008. https://doi.org/10.1016/j.compscitech.2008.01.009

M. Goyat, S. Rana, S. Halder, and P. Ghosh, "Facile fabrication of epoxy-TiO2 nanocomposites: a critical analysis of TiO2 impact on mechanical properties and toughening mechanisms," Ultrasonics sonochemistry, vol. 40, pp. 861-873, 2018. https://doi.org/10.1016/j.ultsonch.2017.07.040

H. A. Al-Turaif, "Effect of nano TiO2 particle size on mechanical properties of cured epoxy resin," Progress in Organic Coatings, vol. 69, no. 3, pp. 241-246, 2010. https://doi.org/10.1016/j.porgcoat.2010.05.011

A. Chatterjee and M. S. Islam, "Fabrication and characterization of TiO2–epoxy nanocomposite," Materials Science and Engineering: A, vol. 487, no. 1-2, pp. 574-585, 2008. https://doi.org/10.1016/j.msea.2007.11.052

A. Kausar, "Performance of corrosion protective epoxy blend-based nanocomposite coatings: a review," Polymer-Plastics Technology and Materials, vol. 59, no. 6, pp. 658-673, 2020. https://doi.org/10.1080/25740881.2019.1673410

R. Yadav, M. Tirumali, X. Wang, M. Naebe, and B. Kandasubramanian, "Polymer composite for antistatic application in aerospace," Defence Technology, vol. 16, no. 1, pp. 107-118, 2020. https://doi.org/10.1016/j.dt.2019.04.008

T. A. Saleh, "Nanomaterials: Classification, properties, and environmental toxicities," Environmental Technology & Innovation, vol. 20, p. 101067, 2020. https://doi.org/10.1016/j.eti.2020.101067

H. . A. Chlob and R. . M. Fenjan, “Studying The Mechanical Properties Of Hybrid Composites Using Natural Additives With Epoxy”, Journal of Engineering and Sustainable Development., vol. 26, no. 1, pp. 15–26, Jan. 2022. https://doi.org/10.31272/jeasd.26.1.2




Submission Dates

Received 13/07/2022

Revised 25/10/2022

Accepted 01/12/2023

How to Cite

Abbas , S. S. ., Raouf , R. M. ., & Al-Moameri, H. . (2024). A REVIEW OF EPOXY-NANOCOMPOSITE PROPERTIES. Journal of Engineering and Sustainable Development, 28(1), 76–95. https://doi.org/10.31272/jeasd.28.1.6