Preparation and Characterization of Nano Composite Materials Based on Polyisoprene Added to Nano Ternary Silica

توصيف المواد المركبة النانوية القائمة على مادة البولي ايزوبرين

Authors

  • Fayq Hasan Jabbar Department of Materials Engineering, College of Engineering, Mustansiriyah University, Baghdad, Iraq. https://orcid.org/0009-0009-1857-5842
  • Fadhil Muhi Mohammed Forensic Science Department, College of Sciences, Al-karkh University of Science, Baghdad, Iraq https://orcid.org/0000-0003-1052-4492

DOI:

https://doi.org/10.31272/jeasd.2305

Keywords:

Fumed Silica, Nano Material, Polymeric Material, Thermal Characterization, Thermogravimetric

Abstract

Polyisoprene (PI), whether naturally or synthetically produced, is used in rubber compounds for many applications, such as tires, belts, and shoes. The effect of Nano ternary silica (NTS) addition on the thermal and mechanical characteristics of PI was investigated in this research. According to the results, the addition of NTS enhances the hardness and mechanical strength of PI, improves thermal properties, reduces thermal deformations, and enhances the ability of the resulting composite materials to withstand high-temperature conditions and resist environmental deformations. The weight percentages for the added NTS in the prepared composite materials followed five models (2 %, 4 %, 6 %, 8 %, and 10 wt. %). The optimal percentage of polyisoprene nanocomposite was determined using X-ray diffraction (XRD), thermogravimetric analysis (TGA), Transmission Electron Microscopy (TEM), and atomic force microscopy (AFM). It was found that at 4 wt.% NTS with a d-spacing between layers of 4.1 nm, the best thermal stability and mechanical properties are obtained. These results suggested that the stability and properties of PI depend on the amount and particle size of the NTS distribution mixture.  

Author Biographies

Fayq Hasan Jabbar, Department of Materials Engineering, College of Engineering, Mustansiriyah University, Baghdad, Iraq.

Fayq Hsan Jabbar, phD chemical engineering

Vice-Chanceller's office for Scientific Affairs

Mustansiriyah University

Fadhil Muhi Mohammed, Forensic Science Department, College of Sciences, Al-karkh University of Science, Baghdad, Iraq

Fadhil Muhi Mohammed,

PhD chemical engineering from university of Manchester, UK

Department of Environmental Science, College of Energy and Environmental Science, Al-karkh University of Science, Baghdad, Iraq,

References

N. Saetung, I. Campistron, S. Pascual, J.-C. Soutif, J.-F. Pilard, and L. Fontaine, “Synthesis of natural rubber-based telechelic cis-1,4-polyisoprenes and their use to prepare block copolymers via RAFT polymerization,” European Polymer Journal, vol. 47, no. 5, pp. 1151–1159,2011. doi: https://doi.org/10.1016/j.eurpolymj.2011.01.013.

F. H. Jabbar and W. A. Latif, “A comparative analysis of various types of modified bentonite clays added to poly methyl butadiene for nanocomposite preparation,” NeuroQuantology, vol. 19, no. 1, pp. 67–71, 2021. doi: 10.14704/nq.2021.19.1.NQ21010

E. P. Collar and J.-M. García-Martínez, Mechanical Behavior of Polymeric Materials: Recent Studies, 2nd ed. Basel, Switzerland: MDPI, 2026. doi: https://doi.org/10.3390/books978-3-7258-6957-2

H. Li, B. Cheng, W. Gao, C. Feng, C. Huang, Y. Liu, P. Lu, and H. Zhao, “Recent research progress and advanced applications of silica/polymer nanocomposites,” Nanotechnology Reviews, vol. 11, no. 1, pp. 2928–2964,2022. doi: https://doi.org/10.1515/ntrev-2022-0484

M. Grayson, Encyclopedia of Composite Materials and Components. New York, NY, USA: John Wiley & Sons, 1983. ISBN: 0471873578.

[Online]. Available: https://ci.nii.ac.jp/ncid/BA0440723X.

L. Wang and S. Tang, “High-performance fiber-reinforced composites: Latest advances and prospects,” Buildings, vol. 13, no. 4, p. 1094, 2023.

doi: https://doi.org/10.3390/buildings13041094.

S. J. Perera, S. M. Egodage, and S. Walpalage, “Enhancement of mechanical properties of natural rubber–clay nanocomposites through incorporation of silanated organoclay into natural rubber latex,” e-Polymers, vol. 20, no. 1, pp. 144–153, 2020.

doi: https://doi.org/10.1515/epoly-2020-0017.

A. T. Naikwadi, B. K. Sharma, K. D. Bhatt, and P. A. Mahanwar, “Gamma radiation processed polymeric materials for high performance applications: A review,” Frontiers in Chemistry, vol. 10, Art. no. 837111, 2022. doi: https://doi.org/10.3389/fchem.2022.837111.

A. Kumar, S. Dixit, S. Singh, S. Sreenivasa, P. S. Bains, and R. Sharma, “Recent developments in the mechanical properties and recycling of fiber-reinforced polymer composites,” Polymer Composites, vol. 46, no. 5, pp. 3883–3908,2025.doi: https://doi.org/10.1002/pc.29261.

V. Mittal, “Thermal characterization of fillers and polymer nanocomposites,” in Characterization Techniques for Polymer Nanocomposites, V. Mittal, Ed. Weinheim, Germany: Wiley-VCH, 2012, pp.13–32.doi: https://doi.org/10.1002/9783527654505.ch2.

M. Alexandre and P. Dubois, “Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials,” Materials Science and Engineering R: Reports, vol. 28, no. 1–2, pp. 1–63, 2000.

doi: https://doi.org/10.1016/S0927-796X(00)00012-7.

A. A. Musa, A. Bello, S. M. Adams, A. P. Onwualu, V. C. Anye, K. A. Bello, and I. I. Obianyo, “Nano-enhanced polymer composite materials: A review of current advancements and challenges,” Polymers, vol. 17, no. 7, Art. no. 893, 2025.

doi: https://doi.org/10.3390/polym17070893.

S. Attia-Essaies, N. Barhoumi, H. Ayachi, H. Bouraoui, and E. Srasra, “Thermal and mechanical performances of unsaturated polyester composites reinforced by natural fillers,” Chemistry Africa, vol. 7, no. 3, pp.1523–1533,2024. doi: https://doi.org/10.1007/s42250-023-00839-5.

L. C. Tran, X. Su, H. Nguyen, L. B. T. La, P. Adu, Q. Jia, I. Lee, H.-C. Kuan, X. Liu, and J. Ma, “Advancing polymer nanocomposites through mechanochemical approaches,” Advanced Nanocomposites, vol. 2, pp. 86–107,2025. doi: https://doi.org/10.1016/j.adna.2025.03.002.

P. Purnama, Z. S. Saldi, and M. Samsuri, “The development of polylactide nanocomposites: A review,” Journal of Composites Science, vol. 8, no. 8, Art.no.317,2024. doi: https://doi.org/10.3390/jcs8080317

N. J. Hameed, “Studying the effect of silica (SiO2) addition on the adhesive properties of polyvinyl alcohol,” Iraqi Journal of Physics, vol. 14,no.29,pp.107–124,2016. doi: https://doi.org/10.30723/ijp.v14i29.227.

S. H. Mohammad, “Studying the mechanical and electrical properties of polyester resin reinforced with silica particles,” Journal of Engineering and Sustainable Development, vol. 17, no. 6, pp. 201–214, 2013.

[Online].Available:https://jeasd.uomustansiriyah.edu.iq/index.php/jeasd/article/view/1041 .

H. A. Alnamel and M. Mudhaffer, “The effect of silicon dioxide nano-filler reinforcement on some properties of heat-cure polymethyl methacrylate denture base material,” Journal of Baghdad College of Dentistry, vol. 26, no. 1, pp. 32–36, 2014.

doi: https://doi.org/10.12816/0015142.

W. Koch and M. C. Holthausen, A Chemist’s Guide to Density Functional Theory. Weinheim, Germany: Wiley-VCH, 2008.

doi: https://doi.org/10.1002/3527600043.

A. T. Numan, K. A. Sanak, E. M. Atiyah, and S. A. Sadiq, “Synthesis and characterization of a new bidentate chalcone ligand type (NO) and its Mn II, Co II, Ni II, and Cu II complexes with study of their antibacterial activity,” Diyala Journal for Pure Sciences, vol. 11, no. 3, pp. 19–30, 2015.[Online]. Available:http://148.72.244.84:8080/xmlui/handle/xmlui/5853.

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Key Dates

Received

2024-11-10

Revised

2026-03-28

Accepted

2026-07-04

Published Online First

2026-04-20

Published

2026-05-01

How to Cite

Jabbar, F. H. ., & Mohammed, F. M. . (2026). Preparation and Characterization of Nano Composite Materials Based on Polyisoprene Added to Nano Ternary Silica: توصيف المواد المركبة النانوية القائمة على مادة البولي ايزوبرين. Journal of Engineering and Sustainable Development, 30(3), 369-372. https://doi.org/10.31272/jeasd.2305

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